Petrology

The study of rocks, their occurrence, composition, and origin. Petrography is concerned primarily with the detailed description and classification of rocks, whereas petrology deals primarily with rock formation, or petrogenesis. Experimental petrology reproduces in the laboratory the conditions of high pressure and temperature which existed at various depths in the Earth where minerals and rocks were formed. A petrological description includes definition of the unit in which the rock occurs, its attitude and structure, its mineralogy and chemical composition, and conclusions regarding its origin. For a discussion of mineral identification, petrographic analysis, and the classification of rocks  See also: Mineralogy; Petrography; Rock

 

Igneous rocks

 

Volcanic rocks are igneous rocks that reach the Earth's surface before solidification. They occur as lavas or as pyroclastic (fragmental) rocks.

Volcanic activity varies greatly in intensity, duration, periods between eruptions, and quantities of gases, liquid rock, and solidified fragments expelled. The important factors influencing these differences are chemical composition of the magma; amount of gas dissolved in it; extent of crystallization or cooling before eruption; and configuration of the conduit and depth to the magma chamber.  See also: Magma

Volcanic structures are of a variety of types (Table 1), influenced by the style of activity of the volcano. Volcanic rocks are presently forming mostly at plate boundaries: at the midocean ridges where voluminous basalts are produced and at convergent plate boundaries (island arcs and continental margins) where most explosive and more silicic volcanism occurs.  See also: Volcano

Intrusive igneous rocks occur in many different types of units or intrusive masses, which are classified chiefly by their shape and structural relations to their wall rocks (Table 2). Bodies that crystallize at great depths (such as batholiths) are referred to as plutonic; those consolidated under shallow cover are designated as hypabyssal.  See also: Pluton

The crystallization of the larger intrusives may result in profound alterations in the adjacent wall rocks (exomorphism). Where stocks and batholiths have invaded sedimentary rocks, an aureole of contact metamorphism is developed. This results from recrystallization under increased temperature and may be accompanied by chemical transformations (pyrometasomatism) produced by hydrothermal solutions generated during the latter stages of magmatic differentiation. Where batholiths have been intruded into rocks which are already regionally metamorphosed, the contact rocks formed are injection gneisses or migmatites.  See also: Contact aureole

Igneous rocks make room for themselves by forceful injection (dilatance), by engulfing wall rock blocks (magmatic stoping), or by subsidence of overlying rocks. The hypothesis of granitization maintains that granites result from the wholesale transformation of sedimentary or metamorphic rock layers by solutions operating through mineral replacement or by ionic emanations acting through solid diffusion.

Blocks of wall rock included in an intrusive mass are xenoliths; their partial destruction by reaction may produce irregular clumps of mafic minerals called schlieren. In some instances such endomorphic effects are sufficiently intensive to result in modification of the composition of the magma (syntexis).  See also: Xenolith

Crystallizing under equilibrium conditions, early magmatic minerals react with remaining fluid to yield new species (Fig. 1). Interruption of the sequence will yield liquid fractions richer in silicon dioxide, alkalis, iron, and water than the original magma, and crystalline fractions richer in calcium and magnesium than the parent magma (magmatic differentiation).

 

 

Fig. 1  Reaction series of Bowen (modified).

 

 

 

fig 1

 

 

 

Igneous rocks occur in distinct associations (Table 3) which can be put in a specific tectonic context. The sources of magma are the mantle and lower crust of the Earth. The diversity of magmas is caused by variations in the source rock, variations in the conditions and depth of origin, differentiation at various depths, assimilation of other rocks by the magma, mixing of two magmas which originated separately, and unmixing (immiscibility) of the melt. A scheme which shows the possible complexity of the origin of common igneous rock associations is given in Table 4.  See also: Igneous rocks

 

Sedimentary rocks

 

Sedimentary rocks are broadly divided into two classes: clastic sediments, such as sandstones and conglomerates, which are composed largely of fragments of preexisting rocks and minerals and chemical sediments, such as evaporites and many limestones, which form as chemical precipitates from oceans or lakes. With the exception of material deposited by glaciers (till or the consolidated form tillite), sedimentary rocks show bedding or stratification. This separation into generally parallel layers (beds, strata) results from sorting according to grain size during deposition, from differences in composition or texture, or from variations in the rate of deposition. The development of most clastic sediments proceeds in the following stages: There is a source rock, any older rock or, for organic sediments, a supply of organically originated material. By weathering, the older rock is mechanically comminuted, chemically altered, or both, to form unconsolidated surficial rock debris called mantle. Particles are transported by streams, ocean and lake currents, wind, glaciers, or by the direct action of gravity which causes particles to slide and roll down slopes. Material moved by rolling, suspension, or solution is deposited. Deposits usually are consolidated by the processes of cementation (sandstones), compaction (shales), and recrystallization (limestones).

Chemical changes accompanying consolidation are termed diagenetic. Weathered material not transported may become a residual sedimentary rock (bauxite). Sedimentary rocks are deposited either on land areas (continental) or in ocean waters (marine). Most marine sedimentation takes place on the submarine extensions of the continents called continental shelves. Examples of types of sedimentary deposits are listed in Table 5. Features characteristically found in sedimentary rocks, in addition to stratification, are cross-bedding, concretions, ripple marks, mud cracks, and fossils.  See also: Diagenesis; Sedimentology; Weathering processes

A formation, which is the basic unit of stratigraphy, is a series of rocks deposited during a specific unit of geologic time and consisting either of a particular rock type or of several types deposited in a sedimentary cycle. Such a cycle is the changing sequence of deposits reflecting, for example, advance or retreat of marine waters in a particular area.

However, while sandstone may be deposited at one time in one place in the sedimentary basin, limestone may be formed simultaneously elsewhere. Such lateral variation in a formation is referred to as facies.  See also: Cyclothem; Facies (geology); Stratigraphy

By means of detailed studies of the fossils of a formation and its lithology, composition, structure, and distribution, the paleoecology of the area may be reconstructed. Correlation of formations is attempted chiefly on the basis of fossils, with supplementary data from the lithology, stratigraphic position, insoluble residues (in acid-soluble rocks), heavy detrital minerals (in clastic rocks) and in drill holes by electrical conductivity, radioactivity, and seismic-wave velocities.  See also: Sedimentary rocks

 

Metamorphic rocks

 

Metamorphism transforms rocks through combinations of the factors of heat, hydrostatic pressure (load), stress (directed pressure), and solutions. Most of the changes are in texture or mineral composition; major changes in chemical composition are called metasomatism. The major types of metamorphism are presented in Table 6. Rocks that can serve as parent material for metamorphic derivatives include igneous, sedimentary, and older metamorphic rocks as well. The complexity of the possible metamorphic mineral assemblages stems not only from the variety of possible parent rocks and from the imposition of the several kinds of metamorphism but also from variation in the intensity of particular types of metamorphism (grade), and from the difficulty of readily achieving chemical equilibrium through solid-state reactions. Various features characteristic of metamorphic rocks include foliation (slaty cleavage, schistosity, and gneissic structure), lineation, banding, and relict structures.  See also: Metamorphism; Metasomatism

The facies principle is employed in attempting to reconstruct the environment under which a metamorphic rock was developed. A metamorphic facies consists of all rocks, without respect to chemical composition, that have been recrystallized under equilibrium, within a particular environment of stress, temperature, load, and solutions. The first two factors are considered critical. The facies are named after metamorphic rocks deemed diagnostic of such restricted conditions. In practice, a group of related rocks of different compositions is assigned to a particular facies upon presence of such a key assemblage. Facies and their type descriptions are as follows:

I. Facies of contact metamorphism. Load pressure low, generally 100–3000 bars (10–300 megapascals). Water pressure highly variable, in some cases possibly exceeding load pressure, in a few cases very low. Facies listed in order of increasing temperature for given range of pressure conditions.

Albite-epidote hornfels.

Hornblende hornfels.

Pyroxene hornfels.

Sanidinite—corresponds to minimum pressures (load, PH2O, PCO2) and maximum temperatures—pyrometamorphism.

 

II. Facies of regional metamorphism. Load and water pressures generally equal and high (3000–12,000 bars or 300–1200 MPa). Facies listed in order of increasing temperature and pressure.

Zeolite (very low grade).

Prehnite-pumpellyite (very low grade).

Greenschist (low grade).

Quartz-albite-muscovite-chlorite.

Quartz-albite-epidote-biotite.

Quartz-albite-epidote-almandine.

Glaucophane schist (represents a divergent line of metamorphism conditioned by development of unusually high pressures at low temperatures).

Almandine amphibolite (medium to high grade).

Staurolite-quartz.

Kyanite-muscovite-quartz.

Sillimanite-almandine.

Granulite (high grade).

Hornblende granulite.

Pyroxene granulite.

Eclogite (very high pressure).

 

Because experimental petrology has allowed the development of a “petrogenetic grid” of mineral reactions, most facies may be subdivided if mineral assemblages are carefully detailed. This subdivision can allow inference of pressure-temperature conditions of metamorphism.

Regional variations in grade may be mapped by means of isograds, lines formed by the intersection of planes of isometamorphic intensity with the Earth's surface. These are defined on the appearance of a specific mineral known to reflect a major increase in the intensity of metamorphism.

The primary cause of stresses acting during regional metamorphism is diastrophism of the mountain-building type. These stresses may precede, accompany, or follow the heating, and the order of thermal and structural events can be unraveled by petrographic study. Most regional metamorphic rocks record several heating and deformation episodes. The higher temperatures may result from deep burial, owing to the geothermal gradient of the Earth, in part to concentrations of radiogenic heat, or in part to heat supplied by cooling masses of magma. In contact metamorphism this last is the sole heat source.  See also: Geologic thermometry

William Ingersoll Rose, Jr.

 

Experimental mineralogy and petrology

 

One aim of mineralogy and petrology is to decipher the history of igneous and metamorphic rocks. Detailed study of the field geology, the structures, the petrography, the mineralogy, and the geochemistry of the rocks is used as a basis for hypotheses of origin. The conditions at depth within the Earth's crust and mantle, the processes occurring at depth, and the whole history of rocks once deeply buried are deduced from the study of rocks now exposed at the Earth's surface. One approach used to test hypotheses so developed is experimental petrology; the term experimental minerals refers to similar studies involving minerals rather than rocks (mineral aggregates).

The experimental petrologist reproduces in the laboratory the conditions of high pressure and high temperature encountered at various depths within the Earth's crust and mantle where the minerals and rocks were formed. By suitable selection of materials the petrologist studies the chemical reactions that actually occur under these conditions and attempts to relate these to the processes involved in petrogenesis.

The experiments may deal with the stability range of minerals and rocks in terms of pressure and temperature; with the conditions of melting of minerals and rocks; or with the physical properties or physical chemistry of minerals, rocks, and rock melts (magmas), or of the vapors, gases, and solutions coexisting with the solid or molten materials. These experiments may thus be related to major geological processes involved in the evolution of the Earth: the conditions of formation of magmas in the mantle and crust and their subsequent crystallization either as intrusions or lava flows; the evolvement of gases by the magmas during their crystallization and the precipitation of ore deposits from some of them; the processes leading to the development of volcanic arcs and mountain ranges; and the metamorphism and deformation of the rocks in the mountain chains, and thus the origin and development of the continents. Representative experimental results are shown in Fig. 2.

 

 

Fig. 2  Selected results in experimental mineralogy and petrology, averaged from many sources. The two geotherms show the temperature distribution with depth in the Earth. The solidus for dry basalt and peridotite provides the upper temperature limit for magma generation to occur in the mantle. The mineral facies of a peridotite upper mantle are shown below the solidus. The lower limit for magma generation is given by the curve granite-H2O. Solid-solid mineral transitions and reactions plotted are quartz-coesite, the breakdown of albite, calcite-aragonite, and the polymorphic transitions among kyanite-andalusite-sillimanite. A decarbonation reaction is shown by the curve for MgCO3 (magnesite), and dehydration reactions are shown for serpentine, for the assemblage muscovite + quartz, and for hornblende in mafic or ultramafic rocks. Note the effect of pressure on the hornblende reaction in the garnet-peridotite facies. 1 kilobar = 102 megapascals; °F = (°C × 1.8) + 32.

 

 

 

fig2

 

 

 

Experimental probes into the Earth

 

The pioneer work of James Hall of Edinburgh on rocks and minerals sealed within gun barrels at high pressures and temperatures earned him the title “father of experimental petrology.” His experiments, published early in the nineteenth century, heralded an era of laboratory synthesis in mineralogy and petrology. Experimental petrology gained tremendous impetus in 1904, when the Geophysical Laboratory was founded in Washington, D.C., and new techniques were developed for the study of silicate melts at carefully controlled temperatures. The results obtained by N. L. Bowen, J. F. Schairer, and others have persuaded most petrologists that physicochemical principles can be successfully applied to processes as complex as those occurring within the Earth, and they have formed the basis for much of the work performed at high temperatures and high pressures. The design of equipment capable of maintaining high temperatures simultaneously with high pressures has been successfully achieved only since about 1950, with a few notable exceptions. The extent of the experimental probe into the Earth varies with the type of apparatus used. The Tuttle cold-seal pressure vessel, or high-pressure test tube, reproduces conditions at the base of the average continental crust. Internally heated, hydrostatic pressure vessels reproduce conditions similar to those just within the upper mantle. Opposed-anvil devices, or simple squeezers, readily provide pressures of 200 kilobars or more, but temperatures attainable are considerably lower than those existing at depths in the Earth corresponding to these pressures.

The deepest experimental probe is provided by a variety of internally heated opposed-anvil devices which can produce pressures of 200 kbar (20 GPa) with simultaneous temperatures of 2000°C (3630°F) or more, although the pressure and temperature measurements become less accurate with the more extreme conditions. This deepest probe produces conditions equivalent to depths of 180–240 mi (300–400 km) in the upper mantle, which are not very deep compared with the 1740-mi (2900-km) depth at the core, but are well within the Earth's outer 300 mi (500 km) where many petrological processes have their origins.  See also: High-pressure mineral synthesis

 

Studies related to Earth structure

 

Geophysical studies and inferences about the compositions of deepseated rocks based on petrological studies of rocks now exposed at the surface, together with laboratory measurements of physical properties of selected materials, provide the basis for theories concerning the composition of the Earth and those parts of the Earth which may be treated as units.  See also: Earth interior

At high pressures, most silicate minerals undergo phase transitions to denser polymorphs, and it is believed that polymorphic transitions within the mantle contribute to the high gradients of seismic-wave velocities occurring at certain depths. Experimental studies of the olivine-spinel transition have been successfully correlated with the beginning of the transition zone of the upper mantle at a depth of about 210 mi (350 km). It has been widely held that the Mohorovičić (M) discontinuity marks a change in chemical composition from basalt of the lower crust to peridotite of the upper mantle, but recent experimental confirmation that basalt undergoes a phase transition to eclogite, its dense chemical equivalent, suggests that the M discontinuity could be a phase transition. This now appears to be unlikely for several reasons, but more detailed experimental studies are required because there remains a strong possibility that this phase transition is involved in tectonically active regions of high heat flow where the M discontinuity is poorly defined.  See also: Moho (Mohorovi^ ić discontinuity)

 

Igneous petrology

 

The Earth's mantle transmits shear waves and is therefore considered to be crystalline rather than liquid; but the eruption of volcanoes at the Earth's surface confirms that melting temperatures are reached at depth in the Earth from time to time and from place to place. One group of experiments is therefore concerned with the determination of fusion curves for minerals believed to exist in the Earth's mantle and of melting intervals for mineral aggregates, or rocks. The position of the solidus curve provides an upper temperature limit for the normal geotherm, and the experiments dealing with melting intervals at various pressures have direct bearing on the generation of basaltic magmas at various depths within the mantle. They also provide insight into the processes of crystallization and fractionation of these magmas during their ascent to the surface. This is one of the major problems of igneous petrology.  See also: Igneous rocks; Magma

Many reactions among silicate minerals are very sluggish, and the presence of water vapor under pressure facilitates the experiments. Water is the most abundant volatile component of the Earth, with carbon dioxide a poor second, and the water in the experiments often plays a role as a component as well as a catalyst. In the presence of water vapor under pressure, melting temperatures of silicate minerals and rocks are markedly depressed, and curves for the beginning of the melting of rocks in the presence of water provide lower limits for the generation of magmas. It is widely believed that many of the granitic rocks constituting batholiths, the cores of mountain ranges, were derived by processes of partial fusion of crustal rocks in the presence of water. The hypothesis appears to be consistent with experimental results on feldspars and quartz in the presence of water at pressures up to 10 kbar (1 GPa) and with similar experiments on plutonic igneous rock series ranging in composition from gabbro to granite. However, evidence suggests that some magmas forming batholiths, and andesite lavas of equivalent composition in tectonically active regions, originated directly from mantle material. Experimental petrologists are therefore extending their studies of the minerals and rocks to granitic and andesitic compositions to pressures greater than 10 kbar (1 GPa), corresponding to upper mantle conditions, with and without water present.  See also: Silicate phase equilibria

The path of crystallization of a magma and the mineral reaction series thus produced are apparently quite sensitive to many variables, including pressure, pressure or fugacity of water, and oxygen fugacity. Techniques have been developed for studying the effect of oxygen fugacity on crystallization paths and also for controlling oxygen fugacity at very low values while the water pressure is simultaneously maintained at very high values.

 

Metamorphic petrology

 

When rocks are metamorphosed, they recrystallize in response to changes in pressure, temperature, stress, and the passage of solutions through the rock. The facies classification is an attempt to group together rocks that have been subjected to similar pressures and temperatures on the basis of their mineral parageneses. The metamorphic facies are arranged in relative positions with respect to pressure (depth) and temperature scales, and the experimental petrologist attempts to calibrate these scales by delineating the stability fields of minerals and mineral assemblages under known conditions in the laboratory. Potentially the most useful reactions for this purpose are solid-solid reactions involving no gaseous phase, such as the reactions among the polymorphs of Al2SiO5, kyanite, sillimanite, and andalusite.

Progressive metamorphism of sedimentary rocks produces a series of dehydration and decarbonation reactions with progressive elimination of water and carbon dioxide from the original clay minerals and carbonates. Experimental determination of these reactions, along with the solid-solid reactions, provides a petrogenetic pressure-temperature grid, in which mineral assemblages occupy pigeonholes bounded by specific mineral reactions. If mineral assemblages in metamorphic rocks are matched with the grid which has been calibrated in the laboratory, this provides estimates of the depth and temperature of the rock during metamorphism. Unfortunately, the temperatures of dissociation reactions are very sensitive to partial pressures of the volatile component involved in the reaction, and therefore there are complications introduced in application of the grid to metamorphic conditions. However, continued experimental studies of the stability of minerals and mineral stabilities under a wide range of laboratory conditions (in the presence of H2O and CO2 gas mixtures, for example, and with oxygen fugacity varied as well) may eventually provide a guide to the composition of the pore fluid that was present during metamorphism. If this composition is known, then the experimental data can be applied with greater confidence.  See also: Metamorphic rocks

Peter J. Wyllie

 

 

Table 1: Types of volcanic structure
Name Characteristics
Shield
Low height, broad area; formed by successive fluid flows accumulating around a single, central vent
Cinder cone
Cone of moderate size with apex truncated; circular in plan, gently sloping slides; composed of pyroclastic particles, usually poorly consolidated
Spatter cone
Small steep-sided cone with well-defined crater composed of pyroclastic particles, well consolidated (agglomerate)
Composite cone
Composed of interlayered flows and pyroclastics; flows from sides (flank flows) common, as are radial dike swarms; slightly concave in profile, with central crater
Caldera
Basins of great size but relatively shallow; formed by explosive decapitation of stratocones, collapse into underlying magma chamber, or both
Plug dome
Domal piles of viscous (usually rhyolitic) lava, growing by subsurface accretion and accompanied by outer fragmentation
Cryptovolcanic structures
Circular areas of highly fractured rocks in regions generally free of other structural disturbances; believed to have formed either by subsurface explosions or sinking of cylindrical rock masses over magma chambers

 

 

 

 

Table 2: Characteristics of intrusive igneous rock masses
Name Shape Structural relations to wall rocks Size and other features
Dikes
Tabular, lensoid
Discordant
Few feet to hundreds of miles long
Sills
Tabular, lensoid
Concordant
Up to several hundred feet thick
Laccoliths
Plano-convex or doubly convex lenses
Generally concordant
1–4 mi (1.5–6.5 km) in diameter; several thousand feet thick
Volcanic necks
Pipelike
Discordant
Few hundred feet to a mile in diameter; cores of eroded volcanoes
Stocks
Irregular, with steep walls
Crosscutting
A small batholith or its upward projection; outcrop area less than 40 mi2(104 km2)
Batholiths
Irregular, contacts dip steeply or outward; no bottoms known
(1) Discordant
Some cover 16,000 mi2(41,000 km2); some composite intrusives of varied petrology
   
(2) Concordant in general, may be crosscutting in detail
 
Plutons
Irregular
Usually crosscutting
Usually large; used as general name for intrusive masses that do not fit other definitions

 

 

Table 3: Igneous rock associations
Name Main rock types Environment
Oceanic basalts
Tholeiitic basalt
Mid-ocean ridges, much of the ocean floor
Spilites
Spilite, keratophyre, pillow basalt
Edges of island arcs; obducted ocean floor
Alkali basalts
Olivine basalt, trachyte, phonolite
Oceanic islands, atectonic continental sites
K-rich basalts
Leucite basalt, trachyte
Isolated atectonic continental sites
Tholeiitic flood basalts
Basalt (generally olivine-free), diabase
Continental flood basalt regions, associated with rifting
Layered mafic intrusives
Gabbro, norite, anorthosite, peridotite
Continental rifting sites
Calc-alkalic volcanic rocks
Basalt, andesite, rhyolite
Convergent plate margins, island arc and continental margin
Alpine peridotites
Peridotite, serpentinite
Convergent plate boundaries
Precambrian anorthosite
Andesine or labradorite anorthosite, norite, syenite, monzonite
Domed pluton of massifs in Precambrian terrains
Granite batholith
(a) Simple: granite, granodiorite
Precambrian shields; cores of mountain
 
(b) Complex: gabbro, tonalite, granodiorite, minor granite
 ranges
Minor granitic intrusive
Granite (some alkalic), quartz syenite, syenite, diorite
Hypabyssal, in mountain ranges and as their outliers
Nepheline syenite
Feldspathoidal rocks, carbonatites
(a) Simple plutons
   
(b) Ring complexes
Lamprophyre
Minette, kersantite, camptonite
Dike swarms

 

 

Table 5: Selected examples of sedimentary deposits under various environments
Agent Deposit Resulting rock
Continental
   
Streams
Valley fill
Sandstone
 
Alluvial fan
Conglomerate
 
Delta
Siltstone
Lakes
Varved clay
Shale
Springs
 
Travertine
   
Siliceous sinter
Swamps
Peat
Coal
Wind
Dune
Sandstone
 
Dust
Loess
 
Volcanic ash
Tuff
Glaciers
Moraine
Tillite
Ground water
Stalactite
Dripstone
Gravity
Talus
Breccia
 
Avalanche
Conglomerate
 
Landslide
 
Marine
   
Breakers and alongshore currents
Beach
Sandstone
   
Conglomerate
Longshore currents
 
Sandstone
   
Shale
Marine organisms
Reefs and other shell deposits
Shell limestone
   
Coquina
   
Diatomite
Marine water
Evaporites
Rock salt
   
Rock anhydrite
Marine water
Colloidal precipitates
Phosphorite
   
Manganese oxide concretions
   
Chert

 

Table 6: Types of metamorphism and their factors
Type Factors Changes in rock
Cataclastic
Stress, low hydrostatic pressure
Fragmentation, granulation
Contact (thermal)
Heat, low to moderate hydrostatic pressure
Recrystallization to new minerals or coarser grains; rarely melting
Pyrometasomatism
Heat, additive hydrothermal solutions, low to moderate hydrostatic pressure
Reconstitution to new minerals; change in rock composition
Regional (dynamic)
Heat, weak to strong stress, moderate to high hydrostatic pressure, ± nonadditive solutions
Recrystallization to new minerals or coarser grains; parallel orientation of minerals to produce foliation

 

 

 

 

 

Bibliography

 

 

T. F. W. Barth, Theoretical Petrology, 2d ed., 1962

M. G. Best, Igneous and Metamorphic Petrology, 2d ed., 2007

K. Bucher and M. Frey, Petrogenesis of Metamorphic Rocks, 7th ed., 2007

G. V. Chilinger, H. J. Bissel, and R. W. Fairbridge (eds.), Carbonate Rocks, 2 vols., 1967

Y. Guegen and V. Palciauskas, Introduction to Rock Physics, 1994

H. H. Hess and A. Poldervaart (eds.), Basalts, 2 vols., 1967

A. Miyashiro, Metamorphic Petrology, 1994

A. Philpotts, Principles of Igneous and Metamorphic Petrology, 1990

P. C. Ragland, Basic Analytical Petrology, 1989

M. Wilson, Igneous Petrogenesis, 1988

J. D. Winter, Introduction to Igneous and Metamorphic Petrology, 2001

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